Crystal structures, spectroscopy and EPR of two distortion isomers of
Cu(II) perchlorate with 2,2 '-bi-imidazoline
A. Mohamadou, G.A. van Albada, W.L. Driessen, R. de Gelder, J. Reedijk
POLYHEDRON
2004, 23, 11, 1969-1973
Abstract:
The synthesis, crystal structures, as well as the electronic and
spectroscopic properties, of two new mononuclear Cu(II) isomeric
compounds containing the ligand 2,2'-bi-imidazoline (biz) are reported.
Both Cu(II) compounds, the blue [Cu(biz)(2)(ClO4)(2)] (1) and the
violet [Cu(biz)(2)](ClO4)(2) (2), have the same stoichiometry and but
differ in the location of the perchlorate anions. The basal plane of
both compounds is formed by four nitrogen atoms of two dichelating biz
ligands. In compound 1, the apical position is occupied by two oxygen
atoms of two perchlorate anions, resulting in an elongated octahedral
geometry around the Cu ion. In compound 2, the perchlorate anions are
not coordinating to the Cu ion, resulting in a square planar geometry
around the Cu atom. Both isomers show different and interesting
H-bonding properties. The electronic, EPR and IR spectroscopy results
are in agreement with the structural geometry. In frozen solution (at
77 K) the EPR spectrum is identical for both compounds, so in that case
they have both the same geometry.